Biosynthetic capacities of actinomycetes. 4. Echinoserine, a new member of the quinoxaline group, produced by Streptomyces tendae.

نویسندگان

  • S Blum
  • H P Fielder
  • I Groth
  • C Kempter
  • H Stephan
  • G Nicholson
  • J W Metzger
  • G Jung
چکیده

A new member of the quinoxaline group antibiotics has been detected by HPLC-diode-array screening. The main compound produced by Streptomyces tendae strain Tü 4031 showed a high degree of similarity in the UV-visible spectral region with echinomycin and their structural similarity was confirmed by structure elucidation using electron tandem mass spectrometry and 2D nuclear magnetic resonance. The new compound, named echinoserine, is a non-cyclic form of echinomycin, but it is not a biosynthetic precursor. Echinoserine is less antibiotically active than echinomycin.

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عنوان ژورنال:
  • The Journal of antibiotics

دوره 48 7  شماره 

صفحات  -

تاریخ انتشار 1995